Estimation of self diffusivity at high density

Input(s)

a: Concentration \(\left(\mathrm{g} \mathrm{mol}^{\mathrm{cm}} \mathrm{cm}^{3}\right)\)

Daa: Prediction of Self-Diffusivity \((\mathrm{g} \mathrm{mol} / \mathrm{cm} \mathrm{s})\)

cDaa \(_{\boldsymbol{r}}\): Reduced Diffusivity ( \(\mathrm{g} \mathrm{mol} / \mathrm{cm} \mathrm{s}\) )

Output(s)

\(\boldsymbol{c D a a}_{\boldsymbol{c}}\): Critical Diffusivity \((\mathrm{g} \mathrm{mol} / \mathrm{cm} \mathrm{s})\)

CDaa: Prediction of Self-Diffusivity \((\mathrm{g} \mathrm{mol} / \mathrm{cm} \mathrm{s})\)

Formula(s)

\[ \begin{aligned} & \mathrm{cDaa}_{\mathrm{c}}=\frac{\mathrm{c} * \text { Daa }}{\mathrm{cDaa}_{\mathrm{r}}} \\ & \mathrm{CDaa}=\left(\mathrm{cDaa}_{\mathrm{c}}\right) *\left(\mathrm{cDaa}_{\mathrm{r}}\right) \end{aligned} \]

Reference(s)

Bird, R.B., Stewart, W.E. and Lightfoot, E.N. (2002). Transport Phenomena (Second Ed.). John Wiley & Sons, Chapter: 17, Page: 523.


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